Praseodymium Calcium Manganate (Pr0.7Ca0.3MnO3) is a doped rare-earth perovskite manganite supplied by Infinita Materials as a high-purity sputtering target for depositing colossal magnetoresistance (CMR) and resistive-switching oxide thin films. As one of the most extensively studied members of the Pr1-xCaxMnO3 family, it combines a charge-ordered antiferromagnetic ground state with field- and voltage-tunable resistivity, properties that researchers and device engineers reproduce directly by sputtering from a compositionally matched ceramic target.
Praseodymium Calcium Manganate crystallises in a distorted orthorhombic perovskite structure (Pnma), with Pr³⁺ and Ca²⁺ sharing the A-site and Mn existing in mixed Mn³⁺/Mn⁴⁺ valence states. Strong coupling among charge, spin, orbital, and lattice degrees of freedom produces charge and orbital ordering, antiferromagnetism, and pronounced resistive responses to magnetic and electrical stimuli. RF magnetron sputtering from stoichiometric ceramic targets enables precise control of Pr: Ca composition and oxygen stoichiometry, which strongly influence switching and charge-ordering behaviour. PCMO thin films are investigated for colossal magnetoresistance, resistive random-access memory (RRAM), memristive and neuromorphic devices, magnetic sensors, and perovskite oxide heterostructures.
Answer: Praseodymium Calcium Manganate is used in thin film deposition for electronic devices, especially in applications requiring high-performance perovskite oxide materials for sensors, magnetic devices, and energy storage.
Answer: It is used as a sputtering target in magnetron sputtering systems to deposit thin films onto substrates, forming functional layers with controlled stoichiometry for device applications.
Answer: It offers excellent control over film composition, enhances electronic and magnetic properties, and allows for producing high-quality films with low impurity levels, improving device performance.
Answer: Because Pr0.7Ca0.3MnO3 is an electrically insulating to semiconducting oxide ceramic, particularly in its low-temperature charge-ordered state, RF magnetron sputtering is the standard approach; conventional DC sputtering is generally unsuitable unless a pulsed-DC supply or special target conditioning is used.
Answer: The x=0.3 composition sits at the point in the Pr1-xCaxMnO3 phase diagram where charge, orbital, and antiferromagnetic ordering coexist with a robust colossal magnetoresistance and resistive-switching response, making it the most extensively characterized and reproducible stoichiometry for thin-film device work.
Praseodymium Calcium Manganate crystallises in a distorted orthorhombic perovskite structure (Pnma), with Pr³⁺ and Ca²⁺ sharing the A-site and Mn existing in mixed Mn³⁺/Mn⁴⁺ valence states. Strong coupling among charge, spin, orbital, and lattice degrees of freedom produces charge and orbital ordering, antiferromagnetism, and pronounced resistive responses to magnetic and electrical stimuli. RF magnetron sputtering from stoichiometric ceramic targets enables precise control of Pr: Ca composition and oxygen stoichiometry, which strongly influence switching and charge-ordering behaviour. PCMO thin films are investigated for colossal magnetoresistance, resistive random-access memory (RRAM), memristive and neuromorphic devices, magnetic sensors, and perovskite oxide heterostructures.
Key Properties of Praseodymium Calcium Manganate
Property
Value
Significance
Crystal structure
Distorted orthorhombic perovskite, space group Pnma
Sets the lattice framework for Jahn-Teller distortion and CE-type charge/orbital ordering exploited in devices
A-site composition
Pr:Ca = 0.7:0.3 (fixed)
Controls the Mn3+/Mn4+ ratio and bandwidth that determine the charge-ordering and Neel temperatures
Electronic ground state
Charge-ordered antiferromagnetic insulator at low temperature; paramagnetic insulator near room temperature
Underlying mechanism for the colossal magnetoresistance and resistive-switching response used in devices
Magnetic ordering / Neel temperature
Antiferromagnetic, charge/orbital-ordered below approximately 170-230 K (sample dependent)
Defines the temperature window in which CMR and charge-ordering effects are strongest
Room-temperature resistivity
Semiconducting to insulating, strongly composition- and oxygen-stoichiometry-dependent
High resistivity makes RF (rather than DC) sputtering the standard deposition method
Thermal conductivity
~1-5 W/m-K
Low value typical of oxide perovskites; relevant to thermal management during extended sputtering runs.
Melting behavior
Decomposes before melting
Constrains target sintering and hot-pressing to temperatures below the decomposition threshold
Target density (theoretical)
~6.5 g/cm3
Used to calculate sputter yield, target mass, and expected erosion life
Types & Grades of Praseodymium Calcium Manganate
Praseodymium Calcium Manganate targets are offered in standard catalogue sizes and grades, with custom purity, density, and geometry available for OEM and R&D deposition systems.
Grade / Form
Typical Purity
Key Features / Uses
Standard catalogue disc
>99.9% (3N)
Stock Dia. 1in x 0.125in and Dia. 2 in. x 0.25 in. discs for routine RF sputtering of CMR and switching test films
High-purity research grade
99.99% (4N)
Reduced trace transition-metal and rare-earth contamination for RRAM and CMR device research
Ultra-high-purity grade
99.999% (5N)
Custom order for fundamental charge-ordering and correlated-electron physics studies requiring minimal impurity scattering
Large-format / custom target
>99.9%, custom purity available
Oversized discs or rectangular plates sized for production-scale magnetron sputtering systems
Bonded target assembly
>99.9%
Target indium- or elastomer-bonded to a copper backing plate for improved heat dissipation during long RF runs
Applications of Praseodymium Calcium Manganate
Sputtered films of Praseodymium Calcium Manganate support demanding roles across research and production applications where this material’s specific structural, electronic, or optical properties are the key requirement.
Industry
Application
Function
Semiconductor memory R&D
Resistive random access memory (RRAM)
Active switching layer whose resistance state is set by applied voltage pulses
Neuromorphic computing
Memristive synaptic elements
Provides analogue, non-volatile resistance states for in-memory and analogue computing architectures.
Large, reproducible resistance change under applied magnetic field for field-sensing devices
Sensor technology
Thermistors and resistance temperature sensors
High temperature coefficient of resistance near the charge-ordering transition enables sensitive thermal sensing.
Academic condensed matter physics
Epitaxial thin films for charge/orbital-ordering studies
Model system for probing strongly correlated electron behaviour in a well-defined thin-film geometry
Advanced microelectronics
Complex oxide heterostructure integration
Functional or buffer layer grown alongside other perovskite oxides such as SrTiO3 and LSMO in multilayer stacks
Why Partner with Infinita Materials?
Technical Depth: in-house quality control with ICP-MS and XRF purity verification, density measurement, and full certificates of analysis on every target.
Global Logistics: reliable supply from single R&D-scale targets to production-line volumes, with established international shipping.
Responsive Support: direct access to materials engineers for grade, bonding, and geometry selection, and process-compatibility questions.
Take the Next Step
Infinita Materials fabricates Praseodymium Calcium Manganate sputtering targets engineered to the purity, density, and geometry your deposition process requires. Whether the requirement is a standard catalog target or a custom size, purity, or bonded assembly, our team can help match the right specification to your deposition system. Request a quote or speak with our technical team to discuss your target specification.
Other Related Product to Praseodymium Calcium Manganate, Pr0.7Ca0.3MnO3
Praseodymium Calcium Manganate is used in thin film deposition for electronic devices, especially in applications requiring high-performance perovskite oxide materials for sensors, magnetic devices, and energy storage.
It is used as a sputtering target in magnetron sputtering systems to deposit thin films onto substrates, forming functional layers with controlled stoichiometry for device applications.
It offers excellent control over film composition, enhances electronic and magnetic properties, and allows for producing high-quality films with low impurity levels, improving device performance.
Because Pr0.7Ca0.3MnO3 is an electrically insulating to semiconducting oxide ceramic, particularly in its low-temperature charge-ordered state, RF magnetron sputtering is the standard approach; conventional DC sputtering is generally unsuitable unless a pulsed-DC supply or special target conditioning is used.
The x=0.3 composition sits at the point in the Pr1-xCaxMnO3 phase diagram where charge, orbital, and antiferromagnetic ordering coexist with a robust colossal magnetoresistance and resistive-switching response, making it the most extensively characterized and reproducible stoichiometry for thin-film device work.
Recommended Products for You
Praseodymium Calcium Manganate, Pr0.7Ca0.3MnO3 Used in Various Industries
Biomedical
Energy
Aerospace
Automotive
Healthcare
Electronics
Latest news & events
Contact sales for any customised requirement
Share your contact info and we’ll get back to you within 24 hours
Request a Quote
High-tech innovation, advanced techniques, and unparalleled quality from Infinita Materials.
Manufactured with advanced methods
High Purity, Density
Homogeneity
Customization
Thank You!
Your Enquiry Successfully Submitted, Our Expert will be reaching out to you soon
Advanced Ceramic Products
Infinita Materials offers advanced ceramic products that perform exceptionally well under extreme conditions. These materials stand apart through superior thermal stability, high wear resistance, and electrical insulation properties. Unlike traditional ceramics, they are engineered for advanced applications in aerospace, semiconductor, and medical industries, ensuring durability, precision, and reliability in demanding environments.
Infinita Materials stands out through its unwavering Commitment to Quality, delivering materials of exceptional purity and performance. These materials use advanced manufacturing techniques explicitly designed for the semiconductor industry to ensure superior compatibility, homogeneity, and consistency. Trusted by engineers and researchers, they are pivotal in driving innovation in research and development, enhancing the impact and efficiency of electronics, chips, semiconductors, and testing processes.
Infinita Materials specializes in custom manufacturing ceramic materials, providing tailored solutions to meet the unique requirements of various industries. Customization includes optimized particle size distribution, surface area, reproducibility, and homogeneity. Our advanced manufacturing techniques ensure consistent quality, durability, thermal performance, and precision. By delivering ceramics that meet specific needs, we support industries with high-performing materials designed for reliability and efficiency.
